Site-selective spectroscopy of Ho3+:KYF4

Abstract
Site‐selective photoluminescence spectroscopy of Ho3+ ions in single‐crystal KYF4, measured with a Fourier‐transform spectrometer at 80 and 2 K sample temperatures, gives evidence for two dissimilar classes of crystal‐field sites. Three similar sites contribute to each class giving a total of six sites in agreement with recent crystallographic results. Analysis of crystal‐field splittings indicates that only one of the classes can contribute to Yb→Ho upconversion green lasing in (Yb,Ho):KYF4.

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