The formation and structure of the novel aluminoxane anion [Me2AlO·AlMe3]22–

Abstract
Trimethylaluminium methylates the cacodylate anion ([AsMe2O2]) with the formation of [AsMe4]2[Me2AlO·AlMe3]2, and an X-ray crystal structure has shown the aluminoxane anion to consist of a planar Al2O2 ring with AlMe3 molecules co-ordinated to the oxygen atoms.

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