THE INTERACTION OF HYDRAZINE WITH BORON AND ALUMINUM HALIDES
Open Access
- 1 August 1963
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 41 (8) , 1872-1876
- https://doi.org/10.1139/v63-275
Abstract
The interaction of boron halides BX3 (where X is Cl or Br) or aluminum halides Al2X6 (where X is Cl, Br, or I) with hydrazine is characterized by the elimination of hydrogen halide and the formation of substances with boron– (or aluminium–) nitrogen linkages. The hydrogen halide appears in the products as hydrazine hydrohalide, which can be separated by a hydrazine washing technique, leaving a polymeric material with empirical formula MN4H5 (where M is Al or B). A reaction scheme is proposed and possible structures of this polymeric product are discussed.Keywords
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