Orientation control in ring opening of an αβ-epoxysilane
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 697-698
- https://doi.org/10.1039/c39760000697
Abstract
1,2-Epoxy-1-trimethylsilylcyclohexane (1) undergoes ring-opening by nucleophilic attack at C- 1 with inversion of configuration; in this way the glycol (2, X = OH), the glycol monoether (2, X = OMe), the bromohydrin (2, X = Br), and the alcohol (2, X = H) have been prepared in high yield.Keywords
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