Acid-catalysed conversion of sulphinamides into sulphinates: a new synthesis of optically active sulphinates
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 568-569
- https://doi.org/10.1039/c39760000568
Abstract
Treatment of sulphinamides with alcohols in the presence of strong acids results in the formation of sulphinates in good yields; this reaction has been shown to proceed with inversion of configuration at the sulphinyl centre and high stereospecificity which is dependent on the structure of the alcohol used.Keywords
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