Linear trinuclear three-centred metal–metal multiple bonds: synthesis and crystal structure of [M3(dpa)4Cl2][M = RuIIor RhII, dpa = bis(2-pyridyl)amidoanion]
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 3,p. 315-316
- https://doi.org/10.1039/cc9960000315
Abstract
The synthesis and X-ray crystal structures of the linear trinuclear metal complexes, [MII 3(dpa)4Cl2](M = Ru or Rh), with a syn–syn bis(2-pyridyl)amido (dpa) ligand, possessing a short M–M–M three-centred multiple bond [Ru–Ru 2.2537(5)Å; Rh–Rh 2.3920(5)Å] are described.Keywords
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