X-Ray Photoelectron Spectra of Aluminum Oxides: Structural Effects on the “Chemical Shift”
- 1 January 1973
- journal article
- research article
- Published by SAGE Publications in Applied Spectroscopy
- Vol. 27 (1) , 1-5
- https://doi.org/10.1366/000370273774333876
Abstract
The aluminum (2p) electron spectra of several anhydrous and “hydrous” aluminum oxides have been recorded, and the binding energies have been measured. A simple electrostatic model is employed to explain the observed shift in binding energy and relate it to differences in structure and hydrogen bonding. Two conclusions can be drawn: structural differences must be considered when interpreting photoelectron spectra for inorganic crystalline substances; and hydrogen bonding with anions may have a measurable effect on the binding energy of core electrons of the cations.Keywords
This publication has 14 references indexed in Scilit:
- Comparison of internal mixing and vacuum deposition procedures for calibrating ESCA [electron spectroscopy for chemical analysis] spectraAnalytical Chemistry, 1972
- Measured binding energy shifts of "3p" and "3d" electrons in arsenic compoundsInorganic Chemistry, 1972
- Determination of Charging Effect in Photoelectron Spectroscopy of Nonconducting SolidsJournal of Applied Physics, 1971
- Verfeinerung der Struktur des Bayerits, Al(OH)3Einschließlich eines Vorschlags für die H-PositionenZeitschrift für Kristallographie, 1967
- Interpretation of the Infrared Spectrum of BoehmiteThe Journal of Chemical Physics, 1965
- Structure of Some Hydroxides and Hydrous Oxides: Binding of Water in some Hydroxides and Hydrous OxidesNature, 1959
- Crystal Structure of BayeriteBulletin of the Chemical Society of Japan, 1958
- Crystal Structure of γ-AlOOH and γ-ScOOHThe Journal of Physical Chemistry, 1956
- Characterization of Hydrated Aluminas by Infrared SpectroscopyAnalytical Chemistry, 1954
- Recent X-Ray Diffraction Studies on the Hydrous Oxides and Hydroxides.The Journal of Physical Chemistry, 1951