Carbon Monoxide Oxidation over Chromium Sesquioxide. III. Kinetics of the Reaction
- 1 November 1976
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 49 (11) , 3018-3022
- https://doi.org/10.1246/bcsj.49.3018
Abstract
Based on the experimental findings in Parts I and II, mechanisms of carbon monoxide oxidation over α-Cr2O3 were proposed with which the reaction takes place simultaneously through two parallel reaction paths. Overall reaction consists of five elementary steps, and the rate constants of all ellementary stepes were determined from the analysis of appropriate transient response data. The simulation of transient response with these rate constants proved the validity of these mechansims and the results of kinetic analyses.This publication has 9 references indexed in Scilit:
- Carbon Monoxide Oxidation over Chromium Sesquioxide. I. Nature of Oxygen Adsorbed on Cr2O3Bulletin of the Chemical Society of Japan, 1976
- Carbon Monoxide Oxidation over Chromium Sesquioxide. II. Adsorption Behavior of CO and CO2Bulletin of the Chemical Society of Japan, 1976
- TRANSIENT RESPONSE METHOD IN HETEROGENEOUS CATALYSISCatalysis Reviews, 1974
- Infrared study of surface properties of .alpha.-chromia. I. Preparation and adsorption of water, heavy water, and carbon monoxideThe Journal of Physical Chemistry, 1971
- Infrared study of surface properties of .alpha.-chromia. III. Adsorption of carbon dioxideThe Journal of Physical Chemistry, 1971
- Infrared studies of CO, O2, and CO2 gases and their interaction products, chemically adsorbed on nickel oxideJournal of Catalysis, 1962
- Infrared Absorption of Zinc Oxide and of Adsorbed CO2. IIThe Journal of Chemical Physics, 1962
- Oxidation Mechanism of Carbon Monoxide on Cr2O3The Journal of the Society of Chemical Industry, Japan, 1960
- The Oxidation of Carbon Monoxide over Chromic OxideThe Journal of Physical Chemistry, 1955