Crystal structure of the aziridinylgallane trimer
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 14,p. 1554-1555
- https://doi.org/10.1039/dt9720001554
Abstract
Crystals of the title compound are orthorhombic, a= 18·364(5), b= 10·823(3), c= 7·114(2)Å, Z= 4 (trimeric units), space group Pnma. The structure was determined from diffractometer data by Patterson and Fourier syntheses, and refined by full-matrix least-squares methods to R 0·077 for 252 observed reflexions. The six-membered (Ga–N)3 ring is in the chair conformation, torsion angles 59—61°, and lies on a crystallographic mirror plane. The mean dimensions are Ga–N 1·97, N–C 1·55, C–C 1·55 Å; N–Ga–N 100, Ga–N–Ga 121, Ga–N–C 116°, angles in three-membered rings ca. 60°.Keywords
This publication has 0 references indexed in Scilit: