Ion Mobility Sensor In Environmental Analytical Chemistry—Concept And First Results

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Abstract
Ion mobility spectrometry is a technique for generating ions at atmospheric pressure via ion-molecule reactions, and for analysing them in an ion drift tube. The time required for the ions to traverse the length of the drift tube is mainly a function of the mass and the charge of the ions. Besides, ion shape and polarizability also affect the drift time. Ion mobility spectrometry does not allow structural identification and quantification of unknown substances in mixtures. However, under certain boundary conditions it provides selective fingerprints of the substances to be observed, and operates at the ppbv concentration level and the millisecond time scale. Through further miniaturization of a recently developed instrument of this type an ion mobility sensor is to be constructed. This sensor includes drift channel, operating shutter, collecting electrode, electronic data acquisition and translation board. The sensor makes possible to obtain real-time ion mobility spectra. We present and discuss the concept of a small ion mobility spectrometer, its operation principle and first results on the way towards its further miniaturization.

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