Synthesis and S-centred reactivity of (C5Me5)3Ru3S4 +
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 1283-1284
- https://doi.org/10.1039/c39940001283
Abstract
Addition of (C5Me5)Ru+ to (C5Me5)2Ru2S4 affords (C5Me5)3Ru3S4 +; this cluster displays S-centred reactivity towards a range of electrophiles (H+, SO2, Me+, Et+) to give adducts with solid-state structures containing Ru3(µ3-S2)(µ3-S)(µ-SR) cores.Keywords
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