Unexpected Chemical and Electrochemical Properties of M3N@C80 (M = Sc, Y, Er)
- 21 April 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 128 (19) , 6480-6485
- https://doi.org/10.1021/ja061035n
Abstract
The unexpected isomerization of N-ethyl [6,6]-pyrrolidino-Y3N@C80 to the [5,6] regioisomer is reported, as well as the synthesis, characterization, and electrochemical analysis of Er3N@C80 derivatives. A complete electrochemical study of the M3N@C80 species (M = Sc, Y, Er) and their derivatives is presented. We introduce electrochemistry as a new tool in the characterization of the [5,6] and [6,6] regioisomers of trimetallic nitride endohedral metallofullerenes.Keywords
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