Copper-Catalyzed Synthesis of Unsymmetrical Triarylphosphines
- 1 May 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 68 (11) , 4590-4593
- https://doi.org/10.1021/jo0343376
Abstract
Various triarylphosphines have been prepared by coupling diphenylphosphine with aryl iodides with catalytic amounts of CuI in the presence of either K2CO3 or Cs2CO3, in good yields. This method can tolerate a variety of functional groups and does not require the use of expensive additives, or harsh reaction conditions, and is palladium free.Keywords
This publication has 29 references indexed in Scilit:
- PH-Functional Phosphines with 1,1‘-Biphenyl-2,2‘-bis(methylene) and 1,1‘-Binaphthyl-2,2‘-bis(methylene) BackbonesInorganic Chemistry, 1998
- Rational Development of Practical Catalysts for Aromatic Carbon−Nitrogen Bond FormationAccounts of Chemical Research, 1998
- Direct Palladium-Catalyzed Phosphinylation of Aryl Triflates with Secondary Phosphines. Its Scope and Limitations: The Synthesis of Optically Active Carboxylated 2-(Diphenylphosphino)-1,1‘-binaphthalenesThe Journal of Organic Chemistry, 1998
- Copper Pnictogenides as Selective Reagents: A New Access to Functionalized Phosphanes and ArsanesAngewandte Chemie International Edition in English, 1997
- A General Copper-Catalyzed Synthesis of Diaryl EthersJournal of the American Chemical Society, 1997
- The Synthesis and Structural Characterization of Mesityldiphenylphosphine, Dimesitylphenylphosphine and TrimesitylphosphineAustralian Journal of Chemistry, 1994
- New Phosphido‐Bridging Copper ClustersAngewandte Chemie International Edition in English, 1993
- Synthesis and reactions of new phosphine - boranesPure and Applied Chemistry, 1993
- Unprecedented stereochemistry of the electrophilic arylation at chiral phosphorusJournal of the American Chemical Society, 1992
- Synthesis and reactions of phosphine-boranes. Synthesis of new bidentate ligands with homochiral phosphine centers via optically pure phosphine-boranesJournal of the American Chemical Society, 1990