Photolysis of sodium anthracene-9-sulphonate and naphthalene-1-sulphonate in aqueous solutions
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1048-1049
- https://doi.org/10.1039/c39760001048
Abstract
Photolysis of sodium anthracene-9-sulphonate (1a) gave 9,10-anthraquinone (5a)via the 9-anthrol anion (3a) by desulphonylation (–SO2; via the n-π* state) and anthracene (2a) by desulphonation (–SO3; via the π–π* state) in aqueous solution; in contrast, sodium naphthalene-1-sulphonate (1b) gave mainly binaphthyl (6b) by desulphonation under similar conditions.Keywords
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