Radical–nucleophilic substitution (SRN1) reactions: preparation and reactions of α-nitrosuiphides
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 1407-1413
- https://doi.org/10.1039/p19800001407
Abstract
α-Nitrosulphides were prepared by SRN1 reaction of 2-bromo-2-nitropropane with thiolate anions, and by SN2 attack of sodium 2-nitropropan-2-ide on symmetrical disulphides. The α-nitrosulphides undergo radicalnucleophilic substitution (SRN1) by nitronate, sulphinate, and malonate anions, but not by thiolate anions.Keywords
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