Normal to relaxor ferroelectric transformations in lanthanum-modified tetragonal-structured lead zirconate titanate ceramics

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Abstract
Lanthanum modified lead zirconate titanate (PLZT) ceramics near a crossover between normal and relaxor ferroelectric states for Zr/Ti ratios of 40/60, 20/80, and 0/100 were investigated by dielectric spectroscopy, Sawyer–Tower polarization techniques and transmission electron microscopy. It was found possible to induce a relaxor state in each of these tetragonal PLZT compositional sequences with increasing La content. The transformation between normal and relaxor‐like behaviors was found to be associated with a domain evolution from normal micron‐sized domains, to tweed‐like subdomain structures, and finally to polar nanodomains. A spontaneous relaxor to normal transformation was found near a critical La content in each compositional sequence. Temperature dependent polarization studies revealed a field‐induced relaxor to normal ferroelectric transition at temperatures above that of the spontaneous transformation.