Electrochemical carbon–carbon coupling of diazomethane ligands
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1071-1072
- https://doi.org/10.1039/c39820001071
Abstract
Carbon–Carbon bond formation via electrochemical coupling of diazoalkane ligands has been investigated; one-electron reduction of trans-[WF(N2CH2)L2]+ in a MeCN electrolyte at a Hg pool cathode affords [L2FW{N2CH2CH2N2}WFL2] in moderate yield (L = Ph2PCH2CH2PPh2).Keywords
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