Spectrochemistry of solutions. Part 12. Cyano-complexes of silver(I) in solution in liquid ammonia
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 4,p. 968-975
- https://doi.org/10.1039/dt9810000968
Abstract
Raman spectra of cyano-complexes of silver(I) in liquid ammonia solution have been interpreted to show the existence, in equilibrium, of the following species: AgCN, AgNC, [Ag(CN)2]–, [Ag(CN)(NC)]–, [Ag(NC)2]–, [Ag(CN)3]2–, [Ag2(CN)]+, [Ag2(CN)2], [Ag2(CN)3]–, [MAg2(CN)5]2–(M = Na+ or K+), and [MAg(CN)3]–(M = Li+, Na+, or K+). The factors affecting the linkage isomerism, ion aggregation, ion pairing, and silver complexation are discussed.Keywords
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