Single-crystal circular dichroism spectra of tris(pentane-2,4-dionato)cobalt(III) and tris(pentane-2,4-dionato)chromium(III)
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 2,p. 291-294
- https://doi.org/10.1039/dt9830000291
Abstract
The axial circular dichroism spectrum of the lowest energy electronic transition has been measured for both Λ-[Co(pd)3](pd = pentane-2,4-dionate) and Λ-[Cr(pd)3] doped in a single crystal of rac-[Rh(pd)3]·nCHCl3(n=ca. 20). The rotational strengths so obtained are compared with those of the corresponding oxalato and 1,2-diaminoethane complexes and an explanation is offered for their relative magnitudes.Keywords
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