FREE RADICALS BY MASS SPECTROMETRY: XXXII. THERMAL DECOMPOSITION OF CYCLOPENTYL RADICALS
Open Access
- 1 March 1965
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 43 (3) , 565-569
- https://doi.org/10.1139/v65-074
Abstract
At low pressures and elevated temperatures cyclopentyl radicals are found to dissociate mainly by two modes of reaction: about 34% by loss of H atom to form cyclopentene, and about 66% by a C—C bond rupture to form ethylene and allyl radicals. Under the conditions employed no evidence for a third possible mode, the loss of H2to form cyclopentenyl radical, could be found. It is estimated that an incidence of 2% of the latter could have been detected.Keywords
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