Stereoselective free radical reactions in the preparation of 2-deoxy-β-D-glucosides
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1461-1463
- https://doi.org/10.1039/c39880001461
Abstract
Decarboxylation of the O-methyl, O-p-cresyl and O-3β-cholestanyl glycosides of 3-deoxy-4,5,7-tri-O-benzyl-D-arabino-heptulosonic acid by means of the derived O-acyl thiohydroxamates leads stereoselectively to the corresponding 2-deoxy-β-D-glucosides.Keywords
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