Silicone as a New Class of Organosilicon Reagent for the Palladium-Catalyzed Cross-Coupling Reaction
- 31 December 2001
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 2001 (06) , 0845-0847
- https://doi.org/10.1055/s-2001-14621
Abstract
Silicone, polyorganosiloxane, serves as an organosilicon reagent for palladium-catalyzed cross-coupling reactions. Treatment of polymethylphenylsiloxane, poly(alkenyl)methylsiloxane, or cyclic oligosiloxanes with various aryl iodides in the presence of silver(I) oxide or tetrabutylammonium fluoride and a catalytic amount of Pd(0) affords the corresponding coupling product in a good to excellent yield.Keywords
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