Vibronic structure of theground state by stimulated emission spectroscopy
- 1 May 1989
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 62 (18) , 2100-2103
- https://doi.org/10.1103/physrevlett.62.2100
Abstract
We report the first observation of the high vibronic levels of the ground state, performed by stimulated emission spectroscopy. The highest cross sections of the process, which uses the E’ ’ state as an intermediate state, are obtained for combinations of symmetric stretch and bending modes. These experimental results are of primary importance for the understanding of energy-level structures in systems exhibiting strong vibronic coupling.
This publication has 23 references indexed in Scilit:
- Spectra in the chaotic region: A quantum analysis of the photodissociation of H+3The Journal of Chemical Physics, 1988
- Molecular Rydberg states: Classical chaos and its correspondence in quantum mechanicsThe Journal of Chemical Physics, 1988
- Periodic orbit analysis of the photodissociation spectrum of H+3The Journal of Chemical Physics, 1988
- Excited states and Jahn–Teller interactions in the sodium trimerThe Journal of Chemical Physics, 1988
- Chaos and dynamics on 0.5–300 ps time scales in vibrationally excited acetylene: Fourier transform of stimulated-emission pumping spectrumPhysical Review Letters, 1987
- Consistent analytic representation of the two lowest potential energy surfaces for Li3, Na3, and K3The Journal of Chemical Physics, 1985
- Vibrationally resolved spectroscopy of sodium clustersSurface Science, 1985
- Electronic properties of alkali trimersThe Journal of Chemical Physics, 1983
- Electronic structure of the sodium trimerMolecular Physics, 1978
- Studies of the Jahn-Teller effect .II. The dynamical problemProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1958