Asymmetric selection via addition. Part 2. Optically active sulphoximides
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 1684-1686
- https://doi.org/10.1039/p19790001684
Abstract
The kinetic resolution of the unsaturated sulphoximides (6)–(10)via addition of the chiral amines (11)–(13) has been examined. The rate of reaction depends strongly on steric effects, to the point that a different reaction, involving breaking of the S–N bond, may occur.Keywords
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