Michael additions to α,β-unsaturated sulphoximides in two-phase systems. Kinetic resolution by means of chiral phase-transfer catalysts
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 2422-2424
- https://doi.org/10.1039/p19800002422
Abstract
Addition of nucleophiles to α,β-unsaturated sulphoximides is a facile reaction in two-phase systems. The chiral phase-transfer catalyst N-benzylquininium chloride is capable of asymmetric selection in the reaction of the α,β-unsaturated sulphoximides with thiols, enantiomeric excesses being in the range 1–13%.Keywords
This publication has 0 references indexed in Scilit: