Infrared Study of the Reaction of CH2 with CO2 in the Solid State
- 1 June 1962
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 36 (11) , 2911-2917
- https://doi.org/10.1063/1.1732401
Abstract
The photolysis of CH2N2 and of CD2N2 in CO2 at temperatures near 50°K has been studied using infrared techniques. Evidence has been obtained for the production of one or more intermediates by the reaction of CH2 with CO2. These intermediates are precursors of H2CO+CO. Possible structures for such species are proposed and discussed.Keywords
This publication has 9 references indexed in Scilit:
- Infrared Spectroscopic Study of the Photolysis of Methyl Azide and Methyl-d3 Azide in Solid Argon and Carbon DioxideThe Journal of Chemical Physics, 1961
- The Bakerian Lecture, The spectra and structures of free methyl and free methyleneProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1961
- Chemiluminescence of Ethylene Formed Probably from Methylene in an Inert MatrixThe Journal of Chemical Physics, 1960
- The Production and Subsequent Photolysis of Transient Products from the Photodecomposition of Diazomethane at 4.2°K.1,2Journal of the American Chemical Society, 1960
- Photochemical Experiments in Rigid Media at Low Temperatures. II. The Reactions of Methylene, Cyclopentadienylene and DiphenylmethyleneJournal of the American Chemical Society, 1959
- Matrix Isolation Studies: Possible Infrared Spectra of Isomeric Forms of Diazomethane and of Methylene, CH2The Journal of Chemical Physics, 1958
- Reactions of Methylene. 2. Ketene and Carbon DioxideJournal of the American Chemical Society, 1958
- Diketene: Infrared Spectrum and Structure. II1Journal of the American Chemical Society, 1957
- Rotational Isomerism as a General Property of Alkyl NitritesThe Journal of Chemical Physics, 1952