Equilibrium properties of polar gases. Part 3.—The second dielectric virial coefficient for mixtures of some polar gases
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 67, 2926-2932
- https://doi.org/10.1039/tf9716702926
Abstract
The interaction second dielectric virial coefficient 12 has been measured for a number of polar gas mixtures. For the mixtures (CH3)2O + CHF3 and (CH3)2O + CHF2Cl, large positive values of 12 are found, probably as a result of hydrogen bonding. None of the intermolecular potential functions proposed will give even a qualitative prediction of the experimental results.Keywords
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