Inverse cycloheptatrienyl sandwich complexes. Crystal structure of [U(BH4)2(OC4H8)5][(BH4)3U(µ-η7,η7-C7H7)U(BH4)3]
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 847-848
- https://doi.org/10.1039/c39940000847
Abstract
The anions [X3U(µ-η7,η7-C7H7)UX3]–(X = NEt2 or BH4) have been obtained by treatment of UX4 with K[C7H9]; the cation [U(BH4)2(thf)5]+ was formed by protonation of [U(BH4)3(thf)3] with [NHEt3][BPh4] in tetrahydrofuran (thf).Keywords
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