Der Interferenzeffekt in der magnetischen Kernrelaxation für Vierspin‐Systeme. V

Publisher Website
Google Scholar
Abstract
The interference of intramolecular dipole‐dipole interaction and anisotropy of electronic screening in nuclear magnetic relaxation is taken into account for systems containing four identical nuclei of spin 1/2 located at the corners of a tetrahedral, a square and a rectangle. The influence of spinrotational interaction is also considered. The results, presented in the paper show that, due to the interference effect, a significant deviation of a pure exponential time dependence of nuclear magnetization in some special cases may appear.