R. A. Robinson Memorial Lecture. Hydration of cation–cation and anion–anion pairs
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Faraday Discussions of the Chemical Society
- Vol. 85, 1-11
- https://doi.org/10.1039/dc9888500001
Abstract
Electrolyte mixture thermodynamics is strongly affected by close interactions between ions with the same sign of charge. Also in suitable cases spin relaxation, electron-transfer kinetics and distinct diffusion coefficients are sensitive to configurations in which the ions in such pairs are so close that their hydration shells interpenetrate or rearrange. Many such close pairs are surprisingly stable.Keywords
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