Cl35 Pure Quadrupole Resonances in Acid Chlorides and Chlorates

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Abstract
The pure quadrupole resonances of Cl35 in acid chlorides of some aliphatic dicarboxylic acids have been observed. No resonances have been found in acid chlorides of aliphatic monocarboxylic acids which retain the unsubstituted CH3 configuration at the chain end not occupied by the COCl group. This absence of resonances is attributed to possible randomness in the crystal structure or thermally activated low-frequency reorientations of groups within the molecule. Resonances have also been measured in several chlorates, sulfuryl chloride, iodine monochloride, iodine trichloride, and selenium tetrachloride. Structural and bonding discussions are given for the latter two compounds.

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