Hindered Rotation in Styryl Anions
- 15 April 1972
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 50 (8) , 1246-1248
- https://doi.org/10.1139/v72-195
Abstract
Magnetically non-equivalent meta-protons, and occasionally ortho-protons, were observed on the benzene ring in styryl anions. With some cations and solvents it was possible to follow the coalescence of the peaks with increasing temperature and obtain Arrhenius activation energies for rotation of the phenyl group.Keywords
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