Different behaviour of cis- and trans-amine-dichloro-(π-ethene)platinum(II) complexes in their reaction with the free amine
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 654-655
- https://doi.org/10.1039/c39780000654
Abstract
The complexes cis-[Pt(π-C2H4)Cl2(L)](L = 3,5-dimethylpyridine or H2NCHMePh) react in solution with two molecules of free L, undergoing substitution of the chlorine trans to ethene and nucleophilic attack on the π-bonded olefin to form cis-[Pt{σ-C2H4(L)}Cl(L)2]Cl species.Keywords
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