Studies on Orchidaceae Glycosides 4. The Structures and Absolute Configurations of cis- and trans-Crassinodine, Two Glucosides from Dendrobium crassinode B. & Rf..

Abstract
Two glucosides, cis- and trans-crassinodine (1 and 2), were found in D. crassinode B. et Rf. Compound 1 was isolated as its tetraacetate. The glucosides 1 and 2 are shown to be the 4R, 5R and 4S, 5R isomers, respectively, of 4-.beta.-D-glucopyranosyloxy-3-methylhex-2-en-5-olide.

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