Friedel-Crafts reactions of some vinylsilanes
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 2485-2489
- https://doi.org/10.1039/p19800002485
Abstract
Substituted cyclohexenylsilanes (2), (5), (9), and (13) undergo Friedel–Crafts reactions to give substitution products, site-selectively at the carbon atom carrying the trimethylsilyl group. β-Trimethylsilylstyrene (17) similarly gives more substitution in Friedel–Crafts reactions with benzoyl chloride and with phenylacetyl chloride than styrene itself. The syntheses of the silanes are reported, and some limitations of the idea identified.Keywords
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