The formation of trichodiene from all-trans-farnesyl pyrophosphate by Trichothecium roseum
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 231b-232
- https://doi.org/10.1039/c3975000231b
Abstract
The isomerization and cyclization of all-trans-farnesyl pyrophosphate (1) to trichodiene (2) by a cellfree system obtained from Trichothecium roseum, takes place with the loss of a pro-1(S) hydrogen atom of farnesyl pyrophosphate and its ultimate replacement with a pro-4(S)-hydrogen atom of NADPH.Keywords
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