Reactions of methylenecyclopropane with some hydridoplatinum(II) complexes
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 12,p. 1736-1739
- https://doi.org/10.1039/dt9780001736
Abstract
Methylenecyclopropane reacts with tram-[PtH(NO3) L2] to give complexes with the (1–3-η-methylallyl)platinum cations [Pt(C4H7)L2]+(L = PEt3, PMe2Ph, or PPh3). When L = PEt3 or PMe2Ph the complexes contain the 1-methylallyl ligand only, but when L = PPh3 the 2-methylallyl isomer is also formed. On the basis of deuterium-labelling studies. mechanisms for these reactions are proposed.Keywords
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