Dipole oscillator strength distributions, sums, and some related properties for Li, N, O, H2, N2, O2, NH3, H2O, NO, and N2O
- 1 December 1977
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Physics
- Vol. 55 (23) , 2080-2100
- https://doi.org/10.1139/p77-252
Abstract
Dipole oscillator strength distributions (DOSDs) have been constructed for ground state Li, N, O, H2, N2, O2, NH3, H2O, NO, and N2O by using experimental and theoretical photoabsoiption and high energy electron inelastic scattering cross sections. Each DOSD is required to satisfy the Thomas–Reiche–Kuhn sum rule and additional constraints derived from available accurate experimental refractivity and dispersion measurements. The DOSDs, the data and procedure used to construct the DOSDs, and the values of the dipole oscillator strength sums Sk and Lk (for a variety of k values) and related atomic and molecular properties obtained from the DOSDs are reported. The discussion includes comments regarding the importance of the constraints imposed on the DOSD with respect to the evaluation of various dipole sums and properties and the accuracy of the results.Keywords
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