Density profiles and pair correlation functions of hard spheres in narrow slits
- 1 March 1997
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review E
- Vol. 55 (3) , 2993-3005
- https://doi.org/10.1103/physreve.55.2993
Abstract
A hard-sphere fluid confined by hard, structureless, and parallel walls is investigated using a certain version of the weighted density-functional theory. The density profile, the excess coverage, the finite-size contribution to the free energy, the solvation force, and the total correlation function are determined as functions of the slit width L for various bulk number densities . In quantitative agreement with rigorous results, the present version of density-functional theory yields a constant and large but finite number density profile for the limiting case that L is reduced to the diameter of the hard spheres. Within the Derjaguin approximation, the results for the slit geometry allows us to obtain the solvation force between two large hard spheres immersed in a fluid of much smaller hard spheres.
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This publication has 42 references indexed in Scilit:
- Structure factor of hard spheres near a wallPhysical Review E, 1996
- Density profiles of colloidal suspensions in equilibrium inside slit poresMolecular Physics, 1996
- Diffuse X-Ray Scattering in Specular Direction: Analysis of a Wetting FilmEurophysics Letters, 1995
- Phase separation of asymmetric binary hard-sphere fluidsPhysical Review Letters, 1991
- Computer simulation of fluids interacting with fluctuating wallsThe Journal of Chemical Physics, 1990
- Phase equilibria of fluid interfaces and confined fluidsMolecular Physics, 1987
- Compressibility route to solvation structureMolecular Physics, 1986
- The distribution of hard rods on a line of finite lengthMolecular Physics, 1986
- Critical surface scattering of x-rays at grazing anglesZeitschrift für Physik B Condensed Matter, 1984
- Critical Surface Scattering of X Rays and Neutrons at Grazing AnglesPhysical Review Letters, 1983