Compounds with bridgehead nitrogen. Part 43. The reaction between trans-2-aminocycloalkanethiols and formaldehyde
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 2777-2781
- https://doi.org/10.1039/p19820002777
Abstract
trans-2-Aminocyclopentanethiol condenses with formaldehyde to give rel-(3aR,6aR,9aR,1 2aR)-6,12-methanoperhydrodicyclopentano [d,i][1,6,3,8]dithiadiazecine whereas trans-2-aminocyclohexanethiol and trans-2-aminocycloheptanethiol give 1 : 1 mixtures of diastereoisomeric bis(perhydrocycloalkanothiazol-3-yl) methanes.Keywords
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