Chelating Bis(thiophosphinic amidate)s as Versatile Supporting Ligands for the Group 3 Metals. An Application to the Synthesis of Highly Active Catalysts for Intramolecular Alkene Hydroamination
- 16 July 2003
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 125 (32) , 9560-9561
- https://doi.org/10.1021/ja021445l
Abstract
Bis(thiophosphinic amidate) complexes (i.e., 1) of representative group 3 and lanthanide metals have been quantiatively prepared in situ from the corresponding thiophosphinic amides and Ln[N(TMS)2]3. These unusual pentacoordinate complexes exhibit very high activity as catalysts for intramolecular alkene hydroamination.Keywords
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