Equilibrium Thermodynamic Properties of the Mixture of Hard Spheres
- 15 February 1971
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 54 (4) , 1523-1525
- https://doi.org/10.1063/1.1675048
Abstract
An equation of state is proposed for the mixture of hard spheres based on an averaging process over the two results of the solution of the Percus–Yevick integral equation for the mixture of hard spheres. Compressibility and other equilibrium properties of the binary mixtures of hard spheres are calculated and they are compared with the related machine‐calculated (Monte Carlo and molecular dynamics) data. The comparison shows excellent agreement between the proposed equation of state and the machine‐calculated data.Keywords
This publication has 21 references indexed in Scilit:
- Perturbation and Variational Approaches to Equilibrium Thermodynamics of Gases, Liquids, and Phase TransitionsIndustrial & Engineering Chemistry, 1970
- Solutions of NonelectrolytesAnnual Review of Physical Chemistry, 1969
- Monte Carlo calculations for one- and two-component fluids in the isothermal-isobaric ensembleChemical Physics Letters, 1969
- Statistical thermodynamics of two-fluid models of mixturesTransactions of the Faraday Society, 1969
- Statistical thermodynamics of mixtures of molecules of different sizesTransactions of the Faraday Society, 1968
- Fifth and Sixth Virial Coefficients for Hard Spheres and Hard DisksThe Journal of Chemical Physics, 1964
- A rigid sphere model for the melting of argonMolecular Physics, 1964
- Exact Solution of the Percus-Yevick Integral Equation for Hard SpheresPhysical Review Letters, 1963
- Thermodynamic properties of mixtures of hard sphere molecules by Monte Carlo methodsTransactions of the Faraday Society, 1963
- A Monte Carlo Equation of State for Mixtures of Hard-Sphere MoleculesNature, 1960