Synthesis of homoserine samples stereospecifically labelled with isotopic hydrogen in the β- and γ-positions
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 143-144
- https://doi.org/10.1039/c39760000143
Abstract
(βR)[β-2H]-L-Homoserine (17) and the (βS)-isomer (8) are synthesised through a sequence involving as key step the formal cis addition of hydroxylamine onto cinnamic acid to form 3-amino-3-phenylpropionic acid; (γR)[γ-2H]-DL-homoserine (20) and the (γS)-isomer (19) are obtained from the enantiomeric forms of stereospecifically labelled 3-phenyl[1-2H]propanol.Keywords
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