Coriolis coupling and the Raman spectra of SF6 and CF4 in the liquid and plastic phases
- 1 August 1976
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 65 (3) , 923-926
- https://doi.org/10.1063/1.433161
Abstract
It is shown how to correct the J model to take account of first order Coriolis coupling on triply degenerate lines of spherical tops. The Debye limit of the J model is examined. Corrected J spectra are then compared to the experimental Raman lines of SF6 and CF4 in their condensed phases.Keywords
This publication has 17 references indexed in Scilit:
- Influence of the coriolis coupling on angular correlation functions of rotating moleculesChemical Physics, 1975
- Raman scattering: Orientational motions and collision frequency in liquid tetrafluoromethane from the triple to the critical pointChemical Physics Letters, 1975
- Vibrational band contours. Part 2.—The second moments of the intensity distribution in bands of symmetric top moleculesJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1975
- Rotational diffusion of spherical top molecules in liquids and gases. IV. Semiclassical theory and applications to the v3 and v4 band shapes of methane in high pressure gas mixturesThe Journal of Chemical Physics, 1974
- Angular correlation functions of spherical-top carbonyl complexes in gaseous N2 influenced by coriolis couplingChemical Physics Letters, 1973
- Raman studies of reorientation of carbon tetrachloride molecules in the liquid and plastic solid phasesChemical Physics, 1973
- Reorientational correlation functions and memory functions in the J-diffusion limit of the extended rotational diffusion modelChemical Physics Letters, 1973
- Absorption dipolaire présentée par les molécules toupies symétriques en phase gazeuse condensée dans le domaine hertzien et infra-rouge lointainMolecular Physics, 1972
- Raman Study of Liquids. I. Theory of the Raman Spectra of Diatomic Molecules in Inert SolutionsPhysical Review A, 1971
- Theory of the Rotational Brownian Motion of a Free Rigid BodyPhysical Review B, 1960