The structural dependence of geminal and vicinal CC coupling constants
- 1 February 1985
- journal article
- research article
- Published by Wiley in Magnetic Resonance in Chemistry
- Vol. 23 (2) , 95-100
- https://doi.org/10.1002/mrc.1260230209
Abstract
CC coupling constants of ten bicyclic hydrocarbons and ten cyclic ethers or carbonyl compounds were determined from the satellites of broad band decoupled spectra or from INADEQUATE measurements. The influences of valence angles, dihedral angles, hybridization and heterosubstitution on geminal and vicinal CC coupling constants are discussed in terms of the algebraic additivity of the contributions from individual coupling paths within the framework of a multiple path mechanism.Keywords
This publication has 31 references indexed in Scilit:
- Der Mehrwegemechanismus bei 13C‐13C‐Fernkopplungskonstanten bicyclischer KohlenwasserstoffeAngewandte Chemie, 1982
- Carbon-13-carbon-13 coupling constants in bicyclic hydrocarbonsJournal of the American Chemical Society, 1982
- Der Mehrwegemechanismus bei 13C‐13C‐Fernkopplungskonstanten cyclischer KohlenwasserstoffeEuropean Journal of Inorganic Chemistry, 1982
- 13C,13C coupling constants of conjugated dienesMagnetic Resonance in Chemistry, 1981
- Investigation of 13C13C long-range couplings in natural-abundance samplesJournal of Magnetic Resonance (1969), 1980
- The conformational dependence of vicinal13C13C spin-spin coupling constants in alicyclic compoundsMagnetic Resonance in Chemistry, 1980
- Influence of the INDO parameterization on the indirect spin-spin coupling constants as calculated by the FPT INDO methodMagnetic Resonance in Chemistry, 1980
- The additivity of NMR carbon-carbon spin-spin coupling constantsMagnetic Resonance in Chemistry, 1979
- Conformational and substituent dependencies of carbon-13-carbon-13 coupling constantsJournal of the American Chemical Society, 1975
- Über Einige Bicyclische Triene mit o‐Dimethylen‐StrukturEuropean Journal of Inorganic Chemistry, 1957