Electrochemical Oxidation of Derivatives of Dibenzodiazepin. Dibenzothiazepin and Dibenzoxazepin
- 1 January 1979
- journal article
- research article
- Published by Taylor & Francis in Analytical Letters
- Vol. 12 (11) , 1217-1234
- https://doi.org/10.1080/00032717908067911
Abstract
Clozapin exhibits two anodic waves at ≥ 1 M H2SO4, but at lower acidities only the first two-electron wave remains. Cyclic voltammetry shows an ECE mechanism. Reversibility decreases at ≥ 10−4 M concentrations, due to formation of an adsorptiob film. In nonaqueous solvents two irreversible one-electron waves appear. Clothiapin and loxapin are more difficultly oxidized and can be measured in the presence of clozapin.Keywords
This publication has 6 references indexed in Scilit:
- Etude Electrochimique et Differenciation de Derives des Dibenzodiazepines et des DibenzothiazepinesAnalytical Letters, 1978
- Electrochemical behavior of the toluidines in aqueous solutionsJournal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1974
- Electrochemical behavior of the aminobenzenesulfonic acids in aqueous solutionsJournal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1973
- Adsorption and kinetics of oxidation of ascorbic acid at platinum electrodesJournal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1972
- Electrochemical behavior of aniline in alkaline solutionsJournal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1971
- Anodic Oxidation Pathways of CarbazolesJournal of the Electrochemical Society, 1968