σ-Inductive interaction through up to fourteen saturated C–C bonds
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 627-628
- https://doi.org/10.1039/c39940000627
Abstract
Analysis of the NMR shifts of unsaturated carbon atoms in monounsaturated linear long-chain esters and acids, including new data from jojoba oil, rules out any explanation in terms of an ‘electric field effect’, but is semiquantitatively consistent with a ‘σ-inductive’ mechanism, having an attenuation factor of 1.75 per saturated C–C bond.Keywords
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