A differential calorimeter for the measurement of heats of solution at high dilutions

1 September 1968

journal article
Published by IOP Publishing in Journal of Physics E: Scientific Instruments

Vol. 1 (9) , 940-943
https://doi.org/10.1088/0022-3735/1/9/313

Abstract

A differential solution calorimeter is described, by means of which heats of solution of non-electrolytes in water can be determined in the mole fraction concentration range 005-20 × 10⁻³. Heats of solution of ethanol and pyridine in water at infinite dilution have been measured and agree well with published data.

Keywords

This publication has 5 references indexed in Scilit:

Enthalpies of mixture of ethanol and water at 25.degree.C
Journal of Chemical & Engineering Data, 1967
Thermochemical Investigations of the Water-Ethanol and Water-Methanol Solvent Systems. I. Heats of Mixing, Heats of Solution, and Heats of Ionization of Water
The Journal of Physical Chemistry, 1966
Calorimetric studies on n-aliphatic alcohol + water and n-aliphatic alcohol + water detergent systems
Transactions of the Faraday Society, 1964
Thermochemical Studies. I. Thermodynamic Functions of Solutions of Pyridine Bases in Water¹
Journal of the American Chemical Society, 1960
Heat of Wetting of Copper, Graphite and Silica Gel
The Journal of Physical Chemistry, 1954