Monocarbaborane anion chemistry. The substantiation of the C-arylated [PhCB6H6]– seven-vertex closo cluster anion by single-crystal synchrotron X-ray diffraction analysis
- 21 June 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 14,p. 2807-2808
- https://doi.org/10.1039/b205016c
Abstract
Single-crystal synchrotron X-ray diffraction analysis of the [NEt4]+ salt of the [2-Ph-closo-2-CB6H6]− anion, obtained from [4-Ph-arachno-4-CB8H13] and NEt3 in refluxing toluene, substantiates the anion as the first structurally characterised seven-vertex monocarbaborane.Keywords
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