Structure and reactivity of a new anionic N-heterocyclic carbene silver(i) complex
- 1 July 2005
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 30,p. 3826-3828
- https://doi.org/10.1039/b506232b
Abstract
The efficient synthesis of aN-benzoyliminoimidazolium ylide provides access to a new type of N-hetereocyclic anionic carbene, from which air stable Ag(I) and Cu(II) complexes and a catalytically active Rh(I) complex were formed.Keywords
This publication has 36 references indexed in Scilit:
- Bent metal carbene geometries in amido N-heterocyclic carbene complexesChemical Communications, 2004
- Structure and Reactivity of an Allylpalladium N-Heterocyclic Carbene Enolate ComplexOrganometallics, 2004
- Anionic Amido N‐Heterocyclic Carbenes: Synthesis of Covalently Tethered Lanthanide–Carbene ComplexesAngewandte Chemie International Edition in English, 2003
- Titanium N-heterocyclic carbene complexes incorporating an imidazolium-linked bis(phenol)Electronic supplementary information (ESI) available: full experimental, NMR and analytical data. See http://www.rsc.org/suppdata/cc/b3/b305745c/Chemical Communications, 2003
- Complexation Promoted Additions to N-Benzoyliminopyridinium Ylides. A Novel and Highly Regioselective Approach to Polysubstituted PiperidinesJournal of the American Chemical Society, 2003
- Organometallic chemistry of silver and copper N‐heterocyclic carbene complexesHeteroatom Chemistry, 2002
- Tridentate Carbene CCC and CNC Pincer Palladium(II) Complexes: Structure, Fluxionality, and Catalytic ActivityOrganometallics, 2001
- A Pd complex of a tridentate pincer CNC bis-carbene ligand as a robust homogenous Heck catalystChemical Communications, 2001
- Olefin Metathesis-Active Ruthenium Complexes Bearing a Nucleophilic Carbene LigandJournal of the American Chemical Society, 1999
- Transition-metal complexes with sulfur ligands. 94. Synthesis and reactivity of nickel, palladium, and platinum complexes with the thiolate carbene ligand 'S2C'2-. X-ray structure determinations of [Ni(PMe3)('S2C')], [Ni(PPh3)('S2C')], [Ni('SC')2], [Pt(PMe3)('S2C')], and ('S2CO')2Inorganic Chemistry, 1993